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Crystalline porous materials: from zeolites to metal-organic frameworks (MOFs)

Zaiku Xie, Bao-Lian Su

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 2,   Pages 123-126 doi: 10.1007/s11705-020-1921-1

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Novel strategies to tailor the photocatalytic activity of metal–organic frameworks for hydrogen generation: a mini-review

Luis A. ALFONSO-HERRERA, Leticia M. TORRES-MARTINEZ, J. Manuel MORA-HERNANDEZ

Frontiers in Energy 2022, Volume 16, Issue 5,   Pages 734-746 doi: 10.1007/s11708-022-0840-x

Abstract: inorganic photocatalysts derived from MOFs.strength of the supramolecular interactions on the photocatalytic performance of bare and MOF-based materialsat the surface of bare materials.of MOFs for PHE.promote synergy between the two materials through strong coordination bonds.

Keywords： metal–organic frameworks (MOFs)     photocatalytic hydrogen evolution     MOF heterojunctions     materials derivedfrom MOFs     bandgap     recombination    

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Research progress of defect-engineered UiO-66(Zr) MOFs for photocatalytic hydrogen production

Frontiers in Energy 2021, Volume 15, Issue 3,   Pages 656-666 doi: 10.1007/s11708-021-0765-9

Abstract: years, defect-engineered Zr-based UiO-66 metal-organic frameworks (UiO-66(Zr) metal-organic frameworks (MOFs)) have shown huge advantages in catalytic, functional materials, adsorption, and other fields due toIt is extremely challenging to introduce defect sites in the synthesis of MOFs to regulate the physicochemicalproperties of materials such as (energy band structure, pore structure, etc.) to obtain an excellentmaterials in order to provide new insights to synthesize high-performance UiO-66(Zr) MOFs materials

Keywords： defect engineering     metal-organic frameworks     UiO-66     photocatalysis    

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Ultrafine Fe-modulated Ni nanoparticles embedded within nitrogen-doped carbon from Zr-MOFs-confined conversion

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 7,   Pages 1114-1124 doi: 10.1007/s11705-021-2087-1

Abstract: Improvement of the low-cost transition metal electrocatalyst used in sluggish oxygen evolution reaction is a significant but challenging problem. In this study, ultrafine Fe-modulated Ni nanoparticles embedded in a porous Ni-doped carbon matrix were produced by the pyrolysis of zirconium metal-organic-frameworks, in which 2,2′-bipyridine-5,5′-dicarboxylate operating as a ligand can coordinate with Ni2+ and Fe3+. This strategy allows formation of Fe-modulated Ni nanoparticles with a uniform dimension of about 2 nm which can be ascribed to the spatial blocking effect of ZrO2. This unique catalyst displays an efficient oxygen evolution reaction electrocatalytic activity with a low overpotential of 372 mV at 10 mA·cm–2 and a small Tafel slope of 84.4 mV·dec–1 in alkaline media. More importantly, it shows superior durability and structural stability after 43 h in a chronoamperometry test. Meanwhile, it shows excellent cycling stability during 4000 cyclic voltammetry cycles. This research offers a new insight into the construction of uniform nanoscale transition metals and their alloys as highly efficient and durable electrocatalysts.

Keywords： metal-organic framework     pyrolysis     ultrafine     Fe-modulated Ni nanoparticles     oxygen evolution reaction    

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Construction of MOFs-based nanocomposite membranes for emerging organic contaminants abatement in water

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 7, doi: 10.1007/s11783-023-1689-x

Abstract:

● Application of the MOF-composite membranes in adsorption was discussed.

Keywords： Emerging organic contaminants     Metal organic frameworks     Synthesis     Adsorption     Catalysis    

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Metal-organic frameworks for CO

Lei ZHANG, Junqing ZHANG

Frontiers in Energy 2019, Volume 13, Issue 2,   Pages 221-250 doi: 10.1007/s11708-019-0629-8

Abstract: Metal-organic frameworks (MOFs) have attracted much attention because of their large surface areas, tunableIn recent years, MOFs have shown much promise in CO photoreduction.Besides, it discussed strategies in rational design of MOF-based photocatalysts (functionalized pristine MOFs, MOF-photosensitizer, MOF- semiconductor, MOF-metal, and MOF-carbon materials composites) with enhanced

Keywords： metal-organic frameworks (MOFs)     photocatalysis     CO2 photoreduction     composite    

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Catalytic process modeling and sensitivity analysis of alkylation of benzene with ethanol over MIL-101(Fe) and MIL-88(Fe)

Ehsan Rahmani, Mohammad Rahmani

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 6,   Pages 1100-1111 doi: 10.1007/s11705-019-1891-3

Abstract: Metal-organic frameworks (MOFs) were modeled to investigate the catalytic performance and existence of

Keywords： MOFs     alkylation     ethylbenzene     catalysts pellet model     kinetic model     sensitivity analysis    

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An Overview of Metal–Organic Frameworks for Green Chemical Engineering Review

Xiang-Jing Kong, Jian-Rong Li

Engineering 2021, Volume 7, Issue 8,   Pages 1115-1139 doi: 10.1016/j.eng.2021.07.001

Abstract: environmental issues resulting from the fast pace of industrialization, the discovery of new functional materialsThe boom in metal–organic frameworks (MOFs) and MOF-derived materials in recent years has stimulatedThe preparation, characterization, and processing of MOF materials are the basis of their full engagementWith intensive research in these topics, it is time to promote the practical utilization of MOFs on anMany famous MOFs have already demonstrated superiority over traditional materials in solving real-world

Keywords： Metal-organic frameworks (MOFs)     Application     Green chemical engineering    

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Metal-organic framework-based CO

Yujie Ban, Meng Zhao, Weishen Yang

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 2,   Pages 188-215 doi: 10.1007/s11705-019-1872-6

Abstract: Metal-organic frameworks (MOFs), as a novel type of porous materials, are being generated at a rapidcapture, and emphasize two importance themes, namely (i) design and modification of CO -philic MOF materials

Keywords： CO2 capture     CO2-philic MOFs     crack-free membranes    

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Hierarchically porous zeolites synthesized with carbon materials as templates

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1444-1461 doi: 10.1007/s11705-021-2090-6

Abstract: From both industrial and scientific perspectives, different carbon materials have been widely employedIn this review, the progress in synthetic strategies using carbon materials as templates is comprehensivelyDirect templates methods, by which the carbon materials are directly mixed with precursors gel as hard

Keywords： hierarchical zeolites     carbon materials     direct templates     indirect templates     carbon-silica composites    

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Influence of envelope insulation materials on building energy consumption

Junlan YANG, Jiabao TANG

Frontiers in Energy 2017, Volume 11, Issue 4,   Pages 575-581 doi: 10.1007/s11708-017-0473-7

Abstract: In this paper, the influence of different external wall insulation materials on the energy consumptionThree types of insulation materials commonly used in Germany including mineral fiber, polyurethane, andenergy analysis model is established to clarify the primary energy use for production of the insulation materialsThe ascending order of the total energy consumption of the three materials is mineral fiber, polyurethaneHowever, the optimum insulation thicknesses for the three insulation materials show a verse order at

Keywords： building envelope     insulation materials     energy consumption     payback time    

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Benzenesulfonic acid-grafted UIO-66 with improved hydrophobicity as a stable Brønsted acid catalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1389-1398 doi: 10.1007/s11705-022-2285-5

Abstract: Hydrothermal and catalytic stability of UIO-66 MOFs with defective structures are critical aspects to

Keywords： metal−organic frameworks (MOFs)     UIO-66     hydrolysis of cyclohexyl acetate     hydrophobicity     Brønsted acidity    

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Emerging electrochemical processes for materials recovery from wastewater: Mechanisms and prospects

Lingchen Kong, Xitong Liu

Frontiers of Environmental Science & Engineering 2020, Volume 14, Issue 5, doi: 10.1007/s11783-020-1269-2

Abstract: Abstract • Mechanisms for selective recovery of materials in electrochemical processes are discussed. • Wastewaters that contain recoverable materials are reviewed. • Application prospects are discussedRecovering valuable materials from waste streams is critical to the transition to a circular economyMunicipal and industrial wastewaters contain a variety of materials, such as nutrients (nitrogen andWe highlight the mechanisms for achieving selective materials recovery in these processes.

Keywords： Materials recovery     Electrosorption     Capacitive deionization     Redox processes     Electrochemical precipitation    

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Promoting hydrogen industry with high-capacity Mg-based solid-state hydrogen storage materials and systems

Frontiers in Energy 2023, Volume 17, Issue 3,   Pages 320-323 doi: 10.1007/s11708-023-0889-1

Abstract: Promoting hydrogen industry with high-capacity Mg-based solid-state hydrogen storage materials and systems

Keywords： materials systems    

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Advanced materials: adsorbent and catalyst for environmental application

Junhua LI, Shubo DENG

Frontiers of Environmental Science & Engineering 2013, Volume 7, Issue 3,   Pages 301-301 doi: 10.1007/s11783-013-0529-9

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Title Author Date Type Operation

Crystalline porous materials: from zeolites to metal-organic frameworks (MOFs)

Zaiku Xie, Bao-Lian Su

Journal Article

Novel strategies to tailor the photocatalytic activity of metal–organic frameworks for hydrogen generation: a mini-review

Luis A. ALFONSO-HERRERA, Leticia M. TORRES-MARTINEZ, J. Manuel MORA-HERNANDEZ

Journal Article

Research progress of defect-engineered UiO-66(Zr) MOFs for photocatalytic hydrogen production

Journal Article

Ultrafine Fe-modulated Ni nanoparticles embedded within nitrogen-doped carbon from Zr-MOFs-confined conversion

Journal Article

Construction of MOFs-based nanocomposite membranes for emerging organic contaminants abatement in water

Journal Article

Metal-organic frameworks for CO

Lei ZHANG, Junqing ZHANG

Journal Article

Catalytic process modeling and sensitivity analysis of alkylation of benzene with ethanol over MIL-101(Fe) and MIL-88(Fe)

Ehsan Rahmani, Mohammad Rahmani

Journal Article

An Overview of Metal–Organic Frameworks for Green Chemical Engineering

Xiang-Jing Kong, Jian-Rong Li

Journal Article

Metal-organic framework-based CO

Yujie Ban, Meng Zhao, Weishen Yang

Journal Article

Hierarchically porous zeolites synthesized with carbon materials as templates

Journal Article

Influence of envelope insulation materials on building energy consumption

Junlan YANG, Jiabao TANG

Journal Article

Benzenesulfonic acid-grafted UIO-66 with improved hydrophobicity as a stable Brønsted acid catalyst

Journal Article

Emerging electrochemical processes for materials recovery from wastewater: Mechanisms and prospects

Lingchen Kong, Xitong Liu

Journal Article

Promoting hydrogen industry with high-capacity Mg-based solid-state hydrogen storage materials and systems

Journal Article

Advanced materials: adsorbent and catalyst for environmental application

Junhua LI, Shubo DENG

Journal Article